712-95-8

Basic information

• Product Name: Benzoic acid, 4-chloro-, 1,1-dimethylethyl ester
• CAS NO: 712-95-8
• Molecular Formula: C11H13ClO2
• Molecular Weight: 212.676
• Mol File: 712-95-8.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-chloro-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-chloro-, 1,1-dimethylethyl ester(712-95-8)
• EPA Substance Registry System: Benzoic acid, 4-chloro-, 1,1-dimethylethyl ester(712-95-8)

Safety Data

• Hazardous Substances Data: 712-95-8(Hazardous Substances Data)

Upstream product

• 1126-46-1 Methyl 4-chlorobenzoate 
• 540-88-5 acetic acid tert-butyl ester 
• 74032-43-2 S-(2-pyridinyl) 4-chlorobenzenecarbothioate 
• 75-65-0 tert-butyl alcohol 
• 140-53-4 p-chlorobenzyl cyanide 
• 13014-48-7 4-chlorobenzoyl cyanide 
• 873-76-7 para-Chlorobenzyl alcohol 
• 75-91-2 tert.-butylhydroperoxide 
• 74-11-3 para-chlorobenzoic acid 
• 1447824-41-0 1-(azido(tert-butylperoxy)methyl)-4-chlorobenzene 
• 201230-82-2 carbon monoxide 
• 106-47-8 4-chloro-aniline 
• 67-56-1 methanol 
• 106-39-8 bromochlorobenzene 

Downstream Products

• 318989-78-5 tert-butyl 4-morpholinyl-4-yl-aminobenzoate 
• 13756-42-8 tert-butyl 4-methylbenzoate 
• 1239384-07-6 1,1,3,3-tetramethyl-1,3-dihydrobenzo[c][1,2]oxasilole 
• 1239384-09-8 3,3-dimethyl-1,1-diisopropyl-1,3-dihydrobenzo[c][1,2]oxasilole 
• 1239384-28-1 4-butylbenzoic acid t-butyl ester 
• 321-37-9 4'-chloro-2,2,2-trifluoroacetophenone 
• 547744-73-0 4-(trimethylsilyl)benzoic acid 1,1-dimethylethyl ester 
• 200125-70-8 (S)-2-methyl-1,2,3,4-tetrahydroquinoline 
• 1780-19-4 (R)-1,2,3,4-tetrahydroquinaldine 
• 1126-46-1 Methyl 4-chlorobenzoate 
• 122-01-0 4-chloro-benzoyl chloride 
• 5894-65-5 N-t-butylbenzamide 
• 1307310-12-8 C₁₂H₁₅NO₃ 
• 1097196-73-0 tert-butyl 4-hydrazinobenzoate 

Relevant articles and documents

Silver/manganese dioxide nanorod catalyzed hydrogen-borrowing reactions and tert-butyl ester synthesis

Silver/manganese dioxide (Ag@MnO2) nanorods are synthesized and characterized by scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, and X-ray photoelectron spectroscopy. It was discovered that Ag@MnO2 nanorods can realize hydrogen-borrowing reactions in high yields and are also effective for the synthesis of tert-butyl esters from aryl cyanides and tert-butyl hydroperoxide in a short period of time. Mechanistic experiments revealed that this catalytic system acts as a Lewis acid in hydrogen-borrowing reactions, while the synthesis of tert-butyl esters occurs through a radical pathway. This is the first report on the excellent catalytic activity of Ag@MnO2 nanorods as a catalyst.

A Cyanide-Free Synthesis of Acylcyanides through Ru-Catalyzed C(sp3)-H-Oxidation of Benzylic Nitriles

A practical method for generation of acylcyanides devoid of any external cyanide sources is presented that relies on a mild Ru-catalyzed selective C?H-oxidation of benzylic nitriles. The starting materials are smoothly generated through condensation of the corresponding carboxylic acid amides using silanes. The obtained acylcyanides can be employed in a plethora of transformation as exemplified to some larger extend in the sequence of C?H-oxidation-Tischenko-rearrangement for the generation of structurally diverse benzoyloxycyanohydrines.

A fast and practical synthesis of tert-butyl esters from 2-tert-butoxypyridine using boron trifluoride·diethyl etherate under mild conditions

A practical direct preparation of tert-butyl esters from 2-tert-butoxypyridine has been developed. This system features the use of boron trifluoride·diethyl etherate in toluene solvent to rapidly achieve the reaction at room temperature. Using this reaction protocol, a variety of tert-butyl esters were synthesized from several different carboxylic acids at high yields. This practical procedure provides a promising and effective approach to the protection of carboxylic acids with a tert-butyl group.