75658-83-2Relevant articles and documents
Enantiotopic-Place Selective C-H Oxidation Using a (Salen)manganese(III) Complex as a Catalyst
Miyafuji, Akio,Katsuki, Tsutomu
, p. 836 - 838 (1997)
A highly enantiotopic-place selective C-H oxidation of cyclic ether (up to 82% ee) was first achieved by using (R,R)-(salen)manganese(III) complex 8 as a catalyst.
Williamson Ether Synthesis with Phenols at a Tertiary Stereogenic Carbon: Formal Enantioselective Phenoxylation of β-Keto Esters
Shibatomi, Kazutaka,Kotozaki, Manato,Sasaki, Nozomi,Fujisawa, Ikuhide,Iwasa, Seiji
supporting information, p. 14095 - 14098 (2015/09/28)
The enantioselective formation of α-aryloxy-β-keto esters is described for the first time. Lewis acid catalyzed enantioselective chlorination of β-keto esters and subsequent SN2 reactions with phenols yielded α-aryloxy-β-keto esters with up to 96 % ee. Favorskii rearrangement of α-chloro-β-keto esters was also found to give 1,2-diesters with slightly reduced enantiopurity.
An efficient oxidative lactonization of 1,4-diols catalyzed by Cp*Ru(PN) complexes
Ito, Masato,Osaku, Akihide,Shiibashi, Akira,Ikariya, Takao
, p. 1821 - 1824 (2008/02/02)
An efficient oxidative lactonization of 1,4-diols in acetone is accomplished by the well-defined ruthenium catalyst, whose bifunctional nature underlies the high efficiency as well as unique chemo- and regioselectivity of the reaction which provides a rapid access to γ-butyrolactones including flavor lactones hinokinin, and muricatacin.