Synthesis of (+/-)-Mesembranol and (+/-)-O-Methyljoubertiamine. Aza-Ring Expansion of cis-Bicyclooctanones

DOI: 10.1021/jo00141a015

Source and publish data:

Journal of Organic Chemistry p. 3881 - 3886 (1982)

Update date:2022-09-26

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Authors:

Jeffs, Peter W.

Cortese, Nicholas A.

Wolfram, Joachim

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Article abstract of DOI:10.1021/jo00141a015

The Syntheses of (+/-)-mesembranol (1) and (+/-)-O-methyljoubertiamine (2) are described.Each synthesis is developed from a regio- and stereospecific heteroannelation sequence of the respective 1-arylcyclohexanes 4 and 10 to provide the 3a-aryl-cis-octahy

Full text of DOI:10.1021/jo00141a015

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