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87-02-5

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87-02-5 Usage

Chemical Properties

Gray needles, white when pure. Soluble in hot water; sparingly soluble in cold water.

Definition

ChEBI: An aminonaphthalenesulfonic acid that is 2-naphthalenesulfonic acid substituted by an amino group at position 7 and a hydroxy group at position 4 respectively.

Flammability and Explosibility

Notclassified

Check Digit Verification of cas no

The CAS Registry Mumber 87-02-5 includes 5 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 2 digits, 8 and 7 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 87-02:
(4*8)+(3*7)+(2*0)+(1*2)=55
55 % 10 = 5
So 87-02-5 is a valid CAS Registry Number.
InChI:InChI=1/C10H9NO4S/c11-7-1-2-9-6(3-7)4-8(5-10(9)12)16(13,14)15/h1-5,12H,11H2,(H,13,14,15)

87-02-5 Well-known Company Product Price

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  • Sigma-Aldrich

  • (08800)  7-Amino-4-hydroxy-2-naphthalenesulfonicacid  technical, ≥90% (T)

  • 87-02-5

  • 08800-100G

  • 946.53CNY

  • Detail

87-02-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 7-amino-4-hydroxy-2-naphthalenesulfonic acid

1.2 Other means of identification

Product number -
Other names 7-Amino-4-hydroxy-2-naphthalenesulfonic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Dyes,Intermediates
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:87-02-5 SDS

87-02-5Synthetic route

6-amino-naphthalene-1,3-disulfonic acid
118-33-2

6-amino-naphthalene-1,3-disulfonic acid

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

Conditions
ConditionsYield
durch Alkalischmelze;
With alkali at 180℃;
naphthalene-1,3,6-trisulfonic acid
86-66-8

naphthalene-1,3,6-trisulfonic acid

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

Conditions
ConditionsYield
With sodium hydroxide anschliessend Erhitzen mit wss. Ammoniak und Schwefeldioxid;
6-amino-naphthalene-1,3-disulfonic acid
118-33-2

6-amino-naphthalene-1,3-disulfonic acid

alkali

alkali

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

Conditions
ConditionsYield
at 160 - 180℃;
pyridine
110-86-1

pyridine

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

acetic anhydride
108-24-7

acetic anhydride

7-(acetylamino)-4-acetyloxynaphthalene-2-sulfonic acid pyridinium salt
1069138-84-6

7-(acetylamino)-4-acetyloxynaphthalene-2-sulfonic acid pyridinium salt

Conditions
ConditionsYield
at 20℃; for 16h;99%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

C20H13N3O8S2(2-)*2Na(1+)

C20H13N3O8S2(2-)*2Na(1+)

Conditions
ConditionsYield
Stage #1: 7-amino-4-hydroxy-2-naphthalenesulfonic acid With hydrogenchloride; sodium nitrite In water at 0 - 5℃; for 1h;
Stage #2: 7-amino-4-hydroxy-2-naphthalenesulfonic acid In water at 0 - 5℃; for 2h; pH=8 - 9;
93.2%
bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

AMI-1
134-47-4

AMI-1

Conditions
ConditionsYield
With sodium hydroxide at 60℃; for 6h; pH=7 - 8;90%
bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4-hydroxy-7-{[(5-hydroxy-7-sulfo-(2-naphthyl))amino]carbonylamino}naphthalene-2-sulfonic acid

4-hydroxy-7-{[(5-hydroxy-7-sulfo-(2-naphthyl))amino]carbonylamino}naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With sodium hydroxide; sodium acetate In tetrahydrofuran; water88%
With sodium acetate In tetrahydrofuran; sodium hydroxide; water
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

C7H5F2NO

C7H5F2NO

C17H11F2N3O5S

C17H11F2N3O5S

Conditions
ConditionsYield
Stage #1: C7H5F2NO With hydrogenchloride; sodium nitrite In water at 0 - 5℃;
Stage #2: 7-amino-4-hydroxy-2-naphthalenesulfonic acid With sodium carbonate In water at 0 - 5℃; for 0.666667h; pH=7.5 - 8.5;
85%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

diphenyl (4'-aminobiphenyl-4-ylamino)(pyridin-3-yl)methylphosphonate
1392848-70-2

diphenyl (4'-aminobiphenyl-4-ylamino)(pyridin-3-yl)methylphosphonate

7-amino-8-((4'-((diphenoxyphosphoryl)(pyridin-3-yl)methylamino)biphenyl-4-yl)diazenyl)-4-hydroxynaphthalene-2-sulfonic acid
1392848-75-7

7-amino-8-((4'-((diphenoxyphosphoryl)(pyridin-3-yl)methylamino)biphenyl-4-yl)diazenyl)-4-hydroxynaphthalene-2-sulfonic acid

Conditions
ConditionsYield
Stage #1: diphenyl (4'-aminobiphenyl-4-ylamino)(pyridin-3-yl)methylphosphonate With hydrogenchloride; sodium nitrite In water at 0℃;
Stage #2: 7-amino-4-hydroxy-2-naphthalenesulfonic acid With sodium hydroxide In water at 0℃; for 0.5h;
83%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

C8H8FNO2

C8H8FNO2

C18H14FN3O6S

C18H14FN3O6S

Conditions
ConditionsYield
Stage #1: C8H8FNO2 With hydrogenchloride; sodium nitrite In water at 0 - 5℃;
Stage #2: 7-amino-4-hydroxy-2-naphthalenesulfonic acid With sodium carbonate In water at 0 - 5℃; for 0.666667h; pH=7.5 - 8.5;
83%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

3-{4-[(E)-2-(2,4-Dichloro-phenyl)-vinyl]-phenyl}-2-mercapto-4-oxo-3,4-dihydro-quinazoline-6-diazonium

3-{4-[(E)-2-(2,4-Dichloro-phenyl)-vinyl]-phenyl}-2-mercapto-4-oxo-3,4-dihydro-quinazoline-6-diazonium

7-Amino-3-(3-{4-[(E)-2-(2,4-dichloro-phenyl)-vinyl]-phenyl}-2-mercapto-4-oxo-3,4-dihydro-quinazolin-6-ylazo)-4-hydroxy-naphthalene-2-sulfonic acid

7-Amino-3-(3-{4-[(E)-2-(2,4-dichloro-phenyl)-vinyl]-phenyl}-2-mercapto-4-oxo-3,4-dihydro-quinazolin-6-ylazo)-4-hydroxy-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With sodium carbonate; sodium chloride In water 1.) 0-5 deg C, 3 h; 2.) 60 deg C;79%
2-(p-aminophenylsulfonyl)ethyl hydrogen sulfate
2494-89-5

2-(p-aminophenylsulfonyl)ethyl hydrogen sulfate

1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

2-amino-1-benzenesulfonic acid
88-21-1

2-amino-1-benzenesulfonic acid

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4-amino-5-hydroxy-2,7-naphthalenedisulfonic acid
90-20-0

4-amino-5-hydroxy-2,7-naphthalenedisulfonic acid

2,4-Diaminobenzenesulfonic acid
88-63-1

2,4-Diaminobenzenesulfonic acid

C43H27ClN12O23S7(6-)*6Na(1+)

C43H27ClN12O23S7(6-)*6Na(1+)

Conditions
ConditionsYield
Stage #1: 1,3,5-trichloro-2,4,6-triazine; 7-amino-4-hydroxy-2-naphthalenesulfonic acid With sodium hydroxide In water at 0 - 5℃; pH=5.6 - 6.5;
Stage #2: With sodium carbonate In water at 3 - 5℃; for 5h;
Stage #3: 2-(p-aminophenylsulfonyl)ethyl hydrogen sulfate; 2-amino-1-benzenesulfonic acid; 4-amino-5-hydroxy-2,7-naphthalenedisulfonic acid; 2,4-Diaminobenzenesulfonic acid Further stages;
77.1%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

phenyl isothiocyanate
103-72-0

phenyl isothiocyanate

4-hydroxy-7-(N'-phenyl-thioureido)-naphthalene-2-sulfonic acid

4-hydroxy-7-(N'-phenyl-thioureido)-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran at 20℃; for 12h;75%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

aniline
62-53-3

aniline

2-phenylamino-5-hydroxynaphthalene-7-sulphonic acid
119-40-4

2-phenylamino-5-hydroxynaphthalene-7-sulphonic acid

Conditions
ConditionsYield
With sodium metabisulfite at 100 - 110℃; pH=4-6; Reagent/catalyst;70.2%
With sodium disulfite
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

phenyl isocyanate
103-71-9

phenyl isocyanate

4-hydroxy-7-(3-phenyl-ureido)-naphthalene-2-sulfonic acid

4-hydroxy-7-(3-phenyl-ureido)-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran at 20℃; for 24h;70%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

methylamine
74-89-5

methylamine

2-(N-methylamino)-5-hydroxynaphthalene-7-sulfonic acid
22346-43-6

2-(N-methylamino)-5-hydroxynaphthalene-7-sulfonic acid

Conditions
ConditionsYield
With sodium metabisulfite at 100 - 110℃; pH=7 - 8; Reagent/catalyst;68.5%
4-chloro-3-nitrophenyl hydroxyethyl sulfone

4-chloro-3-nitrophenyl hydroxyethyl sulfone

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4-(5-hydroxy-7-sulfonaphth-2-yl)-amino-3-nitrophenyl hydroxyethyl sulfone

4-(5-hydroxy-7-sulfonaphth-2-yl)-amino-3-nitrophenyl hydroxyethyl sulfone

Conditions
ConditionsYield
In water60.6%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4,4'-Diaminostilbene dihydrochloride

4,4'-Diaminostilbene dihydrochloride

C34H24N6O8S2(2-)*2Na(1+)

C34H24N6O8S2(2-)*2Na(1+)

Conditions
ConditionsYield
Stage #1: 4,4'-Diaminostilbene dihydrochloride diazotization;
Stage #2: 7-amino-4-hydroxy-2-naphthalenesulfonic acid
43%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

C6H3ClIN2(1+)*Cl(1-)
1608997-54-1

C6H3ClIN2(1+)*Cl(1-)

C22H12Cl2I2N5O4S(1-)*Na(1+)
1608997-57-4

C22H12Cl2I2N5O4S(1-)*Na(1+)

Conditions
ConditionsYield
With sodium hydroxide In water at 0℃; for 2h; pH=9;42%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

urea
57-13-6

urea

2-ureylen-di-N,N'-4-hydroxynaphthalene-2-sulphonic acid monosodium salt
71550-28-2

2-ureylen-di-N,N'-4-hydroxynaphthalene-2-sulphonic acid monosodium salt

Conditions
ConditionsYield
Stage #1: 7-amino-4-hydroxy-2-naphthalenesulfonic acid; urea In water at 100℃; for 16h; Inert atmosphere;
Stage #2: With hydrogenchloride In water at 100℃; for 17h; Inert atmosphere;
15%
1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

2-Amino-5-nitrophenol
121-88-0

2-Amino-5-nitrophenol

C16H12N4O7S

C16H12N4O7S

Conditions
ConditionsYield
Stage #1: 5-Nitro-2-aminophenol With hydrogenchloride; sodium nitrite In water at 0 - 5℃; for 1h;
Stage #2: With aminosulfonic acid In water for 0.05h;
Stage #3: 7-amino-4-hydroxy-2-naphthalenesulfonic acid In water at 10℃; for 2h;
1.3%
carbon disulfide
75-15-0

carbon disulfide

6-amino-4-hydroxy-2-naphthalenesulfonic acid
90-51-7

6-amino-4-hydroxy-2-naphthalenesulfonic acid

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4,4'-dihydroxy-6,7'-thioureylene-bis-naphthalene-2-sulfonic acid

4,4'-dihydroxy-6,7'-thioureylene-bis-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With ethanol; sodium carbonate; sulfur
carbon disulfide
75-15-0

carbon disulfide

1-amino-5-hydroxynaphthalene-7-sulphonic acid
489-78-1

1-amino-5-hydroxynaphthalene-7-sulphonic acid

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4,4'-dihydroxy-7,8'-thioureylene-bis-naphthalene-2-sulfonic acid

4,4'-dihydroxy-7,8'-thioureylene-bis-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With sodium carbonate; sulfur
carbon disulfide
75-15-0

carbon disulfide

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4,4'-dihydroxy-7,7'-thioureylene-bis-naphthalene-2-sulfonic acid

4,4'-dihydroxy-7,7'-thioureylene-bis-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With ethanol; sodium carbonate; sulfur
phosgene
75-44-5

phosgene

6-amino-4-hydroxy-2-naphthalenesulfonic acid
90-51-7

6-amino-4-hydroxy-2-naphthalenesulfonic acid

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4,4'-dihydroxy-6,7'-ureylene-bis-naphthalene-2-sulfonic acid

4,4'-dihydroxy-6,7'-ureylene-bis-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With sodium carbonate
phosgene
75-44-5

phosgene

1-amino-5-hydroxynaphthalene-7-sulphonic acid
489-78-1

1-amino-5-hydroxynaphthalene-7-sulphonic acid

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4,4'-dihydroxy-7,8'-ureylene-bis-naphthalene-2-sulfonic acid

4,4'-dihydroxy-7,8'-ureylene-bis-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With water; sodium carbonate
phosgene
75-44-5

phosgene

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

1-methyl-2,6-diaminobenzene-4-sulphonic acid
98-25-9

1-methyl-2,6-diaminobenzene-4-sulphonic acid

2,6-bis-[N'-(5-hydroxy-7-sulfo-[2]naphthyl)-ureido]-toluene-4-sulfonic acid

2,6-bis-[N'-(5-hydroxy-7-sulfo-[2]naphthyl)-ureido]-toluene-4-sulfonic acid

Conditions
ConditionsYield
With water; sodium carbonate
phosgene
75-44-5

phosgene

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

AMI-1
134-47-4

AMI-1

Conditions
ConditionsYield
With sodium carbonate
phosgene
75-44-5

phosgene

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4-hydroxy-7-ureido-naphthalene-2-sulfonic acid
6421-85-8

4-hydroxy-7-ureido-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With ammonia; water; sodium carbonate at 40 - 50℃;
2-furancarbonyl chloride
527-69-5

2-furancarbonyl chloride

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

7-(furan-2-carbonylamino)-4-hydroxy-naphthalene-2-sulfonic acid
109258-06-2

7-(furan-2-carbonylamino)-4-hydroxy-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With diethyl ether; sodium acetate; sodium carbonate Reagens 4: Wasser;;
benzenediazonium
2684-02-8

benzenediazonium

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

7-amino-4-hydroxy-3-phenylazo-naphthalene-2-sulfonic acid
83006-40-0

7-amino-4-hydroxy-3-phenylazo-naphthalene-2-sulfonic acid

p-nitrobenzenediazonium
14368-49-1

p-nitrobenzenediazonium

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

7,8-diamino-4-hydroxy-naphthalene-2-sulfonic acid
88247-02-3

7,8-diamino-4-hydroxy-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With acetic acid Reduktion des entstandenen Monoazofarbstoffs mit Zinn und Salzsaeure;
thiophosgene
463-71-8

thiophosgene

6-amino-4-hydroxy-2-naphthalenesulfonic acid
90-51-7

6-amino-4-hydroxy-2-naphthalenesulfonic acid

1-hydroxy-6-amino-3-naphthalenesulfonic acid
87-02-5

1-hydroxy-6-amino-3-naphthalenesulfonic acid

4,4'-dihydroxy-6,7'-thioureylene-bis-naphthalene-2-sulfonic acid

4,4'-dihydroxy-6,7'-thioureylene-bis-naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With sodium carbonate

87-02-5Relevant articles and documents

Monoazo compounds having vinylsulfone type fiber reactive group and method for dyeing or printing fiber materials using the same

-

, (2008/06/13)

A monoazo compound of the following formula, STR1 wherein D is phenylene or naphthylene; X is halogeno, pyridinio or STR2 B is --OR3, --SR4, STR3 in which R3, R4, R5 and R6 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, r is 0 or 1, and E is O, SO, SO2, CH2 or NR8, in which R8 is hydrogen or C1 -C4 alkyl; R, R1, R2 and R7 are each hydrogen or alkyl; A1, A2 and A3 are each phenylene, naphthylene or alkylene; Z1, Z2 and Z3 are each --SO2 CH=CH2 or --SO2 CH2 CH2 Y, in which Y is a splittable group; and p is 0 or 1; which compound is useful for dyeing or printing fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.

Copper complexes of 4-fluoro-5-chloropyrimidin-6-yl containing ractive mondazo dyes

-

, (2008/06/13)

The reactive dyes of the formula STR1 in which the substituents and indices have the meaning given in the description, are outstandingly suitable for dyeing or printing naturally occurring or synthetic materials containing hydroxyl or amide groups.

Reactive dyestuffs comprising a triazine moiety and a vinylsulfonyl moiety both being linked by a substituted alkylene bridge member

-

, (2008/06/13)

A reactive dye of the formula STR1 in which: F is a radical selected from the group consisting of metal-free or metal-containing monoazo or disazo dyes containing at least one --SO3 H group, anthraquinone dyes, sulfophthalocyanine dyes, formazan dyes, phenazine dyes, oxazine dyes and nitroaryl dyes, R is hydrogen, C1 -C4 alkyl which is unsubstituted or substituted with --COOH or --SO3 H, cyanoethyl, or hydroxyethyl, X is fluorine, chlorine, bromine, --SO3 H, phenylsulfonyl or C1 -C4 -alkylsulfonyl, p is 1 or 2 and A is a radical of the formula STR2 in which: Y is chlorine, bromine, fluorine, --OH, --OSO3 H, --O-acyl, --CN, --COOH, --COO--C1 -C4 -alkyl, --CONH2 or --SO2 --Z, the group designated "alk" is a straight or branched polymethylene radical having 2 to 6 carbon atoms, V is STR3 hydrogen or C1 -C4 -alkyl which is unsubstituted or substituted by C1 -C2 -alkoxy, carboxyl, sulfo, halogen or hydroxy, Z is β-halogenoethyl, vinyl or β-acetoxyethyl, or A is a radical of the formulae STR4 in all of which R' is C1-6 -alkyl or hydrogen, Z is as defined above, o is 0 to 6, and m is 2 to 6.

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