Natural products, pharmaceutical and photoelectronic materials containing the fluorenone framework
Chemoselective Ruthenium-Catalyzed C-O Bond Activation: Orthogonality of Nickel-and Palladium-Catalyzed Reactions for the Synthesis of Polyaryl Fluorenones
Figure 1
Over the past decade, fluoren-9-one derivatives have attracted considerable attention due to their presence in natural products1 with a range of biological activities (e.g., dengibsin,1d,g dengibsinin,1d dendroflorin,1b cauliphin)1j and in pharmaceutically important agents (anticancer, antioxidant, and anti-HIV).2 Furthermore, fluorenones, arylated fluorenones, and benzofluorenones have been incorporated in oligomers and polymers which have been examined for potential applications of their optical and electrochemical properties as organic light-emitting devices3 and liquid crystals4 (Figure 1).
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