Experimental (EFISH) and Calculated (ZINDO) Data (µ in D, â in 10-30 cm5 esu-1) at 1.907 µm for H2L, [Ni(L)(MePhCHNH2)], and [Ni(HL)(MePhCHNH2)]+

September 13, 2024

• Title:       

  Experimental (EFISH) and Calculated (ZINDO) Data (µ in D,  â in 10-30 cm5 esu-1) at 1.907 µm for H2L, [Ni(L)(MePhCHNH2)], and  [Ni(HL)(MePhCHNH2)]+

• Image Source:

  Synthesis, crystal structures, and nonlinear optical (nlo) properties of new schiff-base nickel(ll) complexes. toward a new type of molecular switch?

• Mark:

  Table 4

• Associated context:

   The NLO data are reported in Table 4.  Besides a tendency for reduced ZINDO-calculated values compared to the EFISH data, it appears clearly that the nickel complex exhibits a lower NLO response (than that of its related ligand) at both experimental and theoretical levels.