Selected Bond Lengths (Å) and Angles (deg) in [Ni(L)(MePhCHNH2)] and [Ni(L)(iPrNH2)] with esd’s in Parentheses
Synthesis, crystal structures, and nonlinear optical (nlo) properties of new schiff-base nickel(ll) complexes. toward a new type of molecular switch?
Table 2
The nickel(II) first coordination sphere is described in Table 2. The averaged metal-ligand bond lengths of 1.866(2) Å are in the same range of magnitude as that of Ni(salen) (1.850(2) Å). The metal atom lies in a nearly square-planar coordination environment and is located 0.0015(3) Å from the O(1), N(1), N(2), N(6) mean plane.
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