The corresponding proton affinity (PA) is compared to those of related amines in Scheme 3 to provide computational support for significant basicity in the -NH-NiII unit

September 13, 2024

• Title:       

  The corresponding proton affinity (PA) is compared to those of related amines in Scheme 3 to provide computational support for significant basicity in the -NH-NiII unit

• Image Source:

  Synthesis, crystal structures, and nonlinear optical (nlo) properties of new schiff-base nickel(ll) complexes. toward a new type of molecular switch?

• Mark:

  Scheme 3

• Associated context:

  The corresponding proton affinity (PA) is compared to those of related amines in Scheme 3 to provide computational support for significant basicity in the -NH-NiII unit. In particular, the protonation at -NH-NiII appears more favorable than that achieved on the primary MePhCHNH2  amine.