The first total synthesis of (+)-spatol (cas 76520-52-0) with natural configuration

Add time:07/13/2019    Source:sciencedirect.com

The first total synthesis of (+)-spatol (1) with natural configuration is described. The important step utilizes the carbon-carbon bond formation with simultaneous epoxide formation by the reaction of optically pure sulfonium ylide (4) and optically pure epoxy aldehyde (5).

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