Total synthesis of (+)-spatol (cas 76520-52-0). A stereospecific construction of vicinal diepoxides from 2,3-epoxy-1,4-diols

Add time:07/14/2019    Source:sciencedirect.com

A total synthesis of (+)-spatol (1) was achieved which depends upon a novel stereospecific transformation of trans-2,3-epoxy-1,4-diols to generate the sensitive allylic vicinal cis-diepoxide in 1.

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