Asymmetric ring-opening reaction of azabenzonorbornadienes with phenols promoted by palladium/(R,R)-DIOP complex
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Add time:07/20/2019 Source:sciencedirect.com
An efficient asymmetric ring opening reaction of azabenzonorbornadienes with various phenols using Palladium/(R,R)-DIOP complex has been demonstrated, the reaction afforded the corresponding products in excellent yields (80–95%) with moderate enantioselectivities (50–64% ees). The syn-configuration of the product was confirmed by the single X-ray crystallography.
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