Vibrational spectra of compounds in the Iodine pentoxide (cas 12029-98-0)-water system and sodium iodate

Add time:07/31/2019    Source:sciencedirect.com

The infra-red spectra of iodine pentoxide, the third hydrate (HI3O8), iodic acid (HIO3), and sodium iodate, have been examined at room temperature and 77°K in the range 4000-40 cm−1. The Raman spectra of iodine pentoxide and the third hydrate have been assigned, and lattice modes discussed. A polymeric structure, rather than the monomeric structure previously suggested, is thought to give a better interpretation of the far infra-red and Raman spectrum of iodine pentoxide, as well as fitting well into the general structural trends for this system. Some of the bands in the vibrational spectra of these compounds have been reassigned.

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