Recovering indium with sulfating roasting from copper-smelting ash

Add time:07/31/2019    Source:sciencedirect.com

A technology for recovering indium from Jinchuan copper-smelting ash was developed. Indium in the ash was first enriched to the leaching-slag in leaching process, and then recovered by sulfating roasting. The method included mixing the leaching-slag with sulfuric acid, making them into particles, roasting the mixture, and then leaching the calcine with hot water. Above 90% of indium in calcine could be dissolved into the leaching solution. The optimized conditions were determined as follows: the mass ratio of sulfuric acid to leaching slag was 0.1, the roasting time was about 1 to 1.5 h in the temperature range of 200–250°C, and the calcine was leached for 1 h with 5:1 of liquid/solid ratio at 60°C. Over 99% of indium in leaching solution was finally enriched by Zn substitution or sulfide precipitation.

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