A new type of indium(III) fluoride complex containing In(III) atoms in both anion and cation: crystal structure and vibrational spectra

Add time:08/02/2019    Source:sciencedirect.com

A new type of fluoride complex of indium(III) [N(CH3)4]6[In(H2O)6][InF6]3·18H2O (1) containing In(III) atoms in the hexafluoride complex anion and the hexaaquacomplex cation has been synthesized and structurally studied. The structure of [N(CH3)4]6[In(H2O)6][InF6]3·18H2O is formed by isolated octahedral complex [In(1)F6]3– and [In(2)F6]3– anions, octahedral complex [In(3)(H2O)6]3+ cations, [N(CH3)4]+ cations, and crystallization H2O molecules. A formation in the structure of 1 of a rather strong O–H···F hydrogen bond between the coordinated H2O molecules of the cation and F atoms of the complex anion with O···F distances of 2.472(1) Å has been established. The synthesized and structurally studied compound 1 is the obtained for the first time indium(III) fluoride complex containing a hexaaquacomplex [In(3)(H2O)6]3+ cation having the configuration of a practically ideal octahedron. The vibrational spectra of the synthesized compound have been discussed with taking into account the results of crystal structure studies.

We also recommend Trading Suppliers and Manufacturers of INDIUM SULFATE (cas 10294-68-5). Pls Click Website Link as below: cas 10294-68-5 suppliers

Prev:Selective recovery of indium from iron-rich solutions using an Aliquat 336 iodide supported ionic liquid phase (SILP)
Next:(2,2′-bipy)[In2(OH)2(H2O)](SO4)2: The first INDIUM SULFATE (cas 10294-68-5) with a layer structure)