Mössbauer study of deuteration effects on some ferrous hexammine salts

Add time:07/29/2019    Source:sciencedirect.com

The quadrupole splitting ϵ was measured between 90 and 350 K for the compounds Fe(NH3)6X2 and Fe(ND3)6Cl2 where X = Cl, BF4 and SiF6. At 100 K the tetrafluoroborate shows a relative isotope effect {ϵ(deuterated) - ϵ(hydrogenated)}/ϵ(hydrogenated) of about 10%. In the case of the tetrafluoroborate, too, the isotope effect is strongly temperature dependent and represents 20% of the temperature variation of ϵ(Fe(NH3)6(BF4)2). For the chloride and hexafluorosilicate the results are less impressive.

We also recommend Trading Suppliers and Manufacturers of FERROUS HEXAFLUOROSILICATE (cas 12062-25-8). Pls Click Website Link as below: cas 12062-25-8 suppliers

Prev:Fluoroferric hexafluorosilicates obtained in the reaction of Fe(OH)3 with H2SiF6 and in the oxidation of FeSiF6 with H2O2
Next:Novel Nanoporous Carbon/Iron Oxide Catalyst for SO2 Degradation)