Autoxidative ringverengung von 1,2-bis(trimethylsiloxy)-cyclobutenen
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Add time:08/02/2019 Source:sciencedirect.com
1,2-Bis(trimethylsiloxy)cyclobutenes undergo facile autoxidative ring contraction yielding 1-trimethylsiloxycyclopropane carboxylic acid trimethylsilyl esters as major products. The results are discussed in terms of a mechanism involving electron transfer and intermediate formation of dioxiranes.
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