Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol

Add time:07/29/2019    Source:sciencedirect.com

The new complex [Cu2(H2L)Cl3] with axial chloride ions coordination based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol was obtained and its crystal structure was determined. Magnetic studies revealed the presence of antiferromagnetic exchange interaction of −193 cm−1 that is extremely high for such type of complexes. The quantum chemical calculation of 2J value has perfectly matched an experiment.

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