Perchlorinated europium, terbium and lutetium mono(phthalocyaninates): Synthesis, investigation of thermal stability and optical properties
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Add time:07/29/2019 Source:sciencedirect.com
A novel hexadecachloro-substituted terbium(III)phthalocyaninate was synthesised and identified by mass-spectrometry, infrared and UV–Vis spectroscopies. Its elemental composition was proved using high resolution mass spectrometry, while thermal analysis revealed sufficiently high thermal stability up to 220 °C. For the first time for lanthanide(III)mono(phthalocyaninates), the influence of the lanthanide ion nature on the nonlinear optical properties was investigated. The values of the absorption cross-sections of the first excited state were determined using the z-scan technique. The highest value (σ1 = 1.96 × 10−16 cm2) was observed for the terbium complex.
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