Asymmetric synthesis of the ab-ring of aklavinone (cas 16234-96-1)
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Add time:08/02/2019 Source:sciencedirect.com
A formal synthesis of the AB-ring of aklavinone 3 was achieved via the asymmetric synthesis of diol 8 prepared in three steps from tetralone 5. The crucial step involved the asymmetric hydroxylation of 5 in ≥ 95% ee using (camphorylsulfonyl)oxaziridine derivative (+)-4b.
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