Chemoenzymatic approach to the AB ring system of aklavinone (cas 16234-96-1)
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Add time:08/04/2019 Source:sciencedirect.com
Both enantiomers of compound 3, a possible intermediate for the AB ring system 2 of Aklavinone 1, were obtained in optically active form from diol 7. Key steps were the preparation of both enantiomers of monoacetate 8d, via enzymatic reactions that utilize PPL as catalyst, and the construction of ring A in a totally regioselective manner.
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