Thiolato-bridged tetra- and hexa-nuclear ruthenium(II) carbonyl chloro complexes
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Add time:08/08/2019 Source:sciencedirect.com
Two aryl-thiolato-bridged ruthenium carbonyl chloro clusters were synthesized from reactions of [Ru(CO)2(μ-Cl)2]n and sodium arylthiols. The tetra- and hexa-nuclear clusters display unique eight and twelve metallomacrocycle rings with Ru4S4 and Ru6S6 cores, respectively.
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