Enthalpies of solution and solubilities of tin(IV) iodide and of germanium(IV) iodide

Add time:08/13/2019    Source:sciencedirect.com

Enthalpies of solution of tin(IV) iodide and of germanium(IV) iodide are reported for a variety of polar and non-polar solvents. Correlations with Gutmann donor numbers and enthalpies of vaporisation are discussed. Solubilities of tin(IV) iodide and of germanium(IV) iodide are reported in a range of non-polar solvents, at 298.2 K. These and earlier results, for these compounds and for silicon(IV) iodide and iodine, are discussed by regular solution theory in terms of Hildebrand's solubility parameter δ. Entropies of solution have been calculated for tin(IV) iodide dissolving in non-polar solvents.

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