Synthesis, structure and photoluminescent properties of BF2 and BPh2 complexes with N,O-benzazine ligands
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Add time:08/15/2019 Source:sciencedirect.com
Novel N,O-bidentate BF2 and BPh2 complexes have been prepared in good to excellent yields through coordination of 8-hydroxy-2-methylquinolines and 2-(2-hydroxyphenyl)-3Н-quinazolin-4-ones with boron trifluoride etherate or triphenylborane under mild conditions. All complexes have been characterized by 1H, 11B and 19F NMR, mass-spectrometry and X-ray crystallography data. Some complexes have been found to exhibit a significant fluorescence in acetonitrile solutions. Electronic and site effects of substituents in both heterocyclic and phenol fragments proved to have a profound impact on quantum yields.
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