Interconversion of boranes—IV a kinetic study of the decomposition of tetraborane-10☆
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Add time:08/11/2019 Source:sciencedirect.com
The kinetic study of the thermal decomposition of tetraborane-10 in the presence of carbon monoxide revealed that the reaction was approximately first order in tetraborane-10 and zero order in carbon monoxide. The heat of activation of the reaction was found to be 24,560 cal per mole. The close correspondence between the rate constants for this reaction and those previously determined for the conversion of tetraborane-10 to pentaborane-11 in the presence of diborane coupled with the fact that tetraborane-8 carbonyl is the major product of the reaction strongly suggests that tetraborane-8 is the intermediate in both reactions.
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