Interconversion of boranes—I A kinetic study of the conversion of tetraborane-10 to pentaborane-11
-
Add time:08/17/2019 Source:sciencedirect.com
Kinetic studies of conversion of B4H10 to B5H11 are reported. The rate equation Rate = 6·5 × 1013 exp (−24300RT)(B4H10) is interpreted in terms of the two step reaction B4H10 → B4H8 + H2B4H8 + B2H6 → B5H11 + BH3 wherein the first step is rate limiting.Application of semitopological equations (modified to treat vacant orbital structures) leads to two satisfactory structures for B4H8.
We also recommend Trading Suppliers and Manufacturers of Tetraborane(10). (cas 18283-93-7). Pls Click Website Link as below: cas 18283-93-7 suppliers
Prev:A new silyl substituted arachno-tetraborane(8) derivative
Next:The reaction of ethylene with tetraborane: The preparation, structure and properties of dimethylenetetraborane) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Studies on tetraborane(8) carbonyl, B4H8·CO: its isomeric composition in the gas phase and in solution, and its reactions with alkenes108/19/2019
- The reaction of ethylene with tetraborane: The preparation, structure and properties of dimethylenetetraborane08/18/2019
- A new silyl substituted arachno-tetraborane(8) derivative08/16/2019
- 2,4-Ethanotetraborane derivatives. 3.[1] determination of the molecular structure of 2,4-(t-butylethano)tetraborane(10), 2,4-(ButCHCH2)B4H8, in the gas phase by electron diffraction08/15/2019
- The UV spectra of tetraborane(10) and pentaborane(9) in the gas phase08/14/2019
- Diborane–tetraborane conversion in C60 vesicles—a theoretical study08/13/2019
- Theoretical study of the structure of tetraborane(10)08/12/2019
- Interconversion of boranes—IV a kinetic study of the decomposition of tetraborane-10☆08/11/2019
