A new procedure for the preparation of 2-vinylindoles and their [4+2] cycloaddition reaction

Add time:08/17/2019    Source:sciencedirect.com

A new approach for the synthesis of 2-vinylindole derivatives by 5-exo mode cyclization of 2-(3-silyloxymethylallenyl)anilines was developed. The starting allenylanilines were easily prepared by the Stille coupling of o-iodoaniline and allenylstannanes. The formed 2-vinylindole derivatives were transformed into several carbazole derivatives via the [4+2] cycloaddition reaction with suitable dienophiles.

We also recommend Trading Suppliers and Manufacturers of 2-(7-Octyn-1-yl)-1H-isoindole-1,3-dione (cas 17170-26-2). Pls Click Website Link as below: cas 17170-26-2 suppliers

Prev:Synthesis of substituted tropones by sequential Rh-catalyzed [5+2] cycloaddition and elimination
Next:XPS and structural studies of high quality graphene oxide and reduced graphene oxide prepared by different chemical oxidation methods)