Research paperA new Ni(dmit)2-based organic magnetic charge-transfer salt, (m-PO-CONH-N-methylpyridinium)[Ni(dmit)2]·CH3CN

Add time:08/15/2019    Source:sciencedirect.com

A new Ni(dmit)2-based organic magnetic charge-transfer (CT) salt, (m-PO-CONH-N-methylpyridinium)[Ni(dmit)2]·CH3CN, where PO = 2,2,5,5-Tetramethyl-3-pyrrolin-1-oxyl free radical and dmit = 2-Thioxo-1,3-dithiole-4,5-dithiolate, was obtained, the crystal structure and magnetic properties of which are reported. Magnetic susceptibility of the CT salt obeys a combination of 1D ferromagnetic (1DF) Heisenberg (J1DF = +0.26 K) and Singlet-Triplet (ST) models (JST = −51.2 K) with mean field (MF) approximation (JMF = −6.7 K), suggesting that spins on the PO radicals form 1D ferromagnetic chains and spins on the Ni(dmit)2 monoanions form spin dimers at low temperature, the latter of which was also confirmed by band calculations.

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