Synthesis, crystal structure of (2-methylpyridinium)2[TbCl4(H2O)3]Cl and magnetic behaviour of (2-methylpyridinium)2[TbCl4(H2O)3]Cl and (2-methylpyridinium)3[TbCl6]

Add time:08/17/2019    Source:sciencedirect.com

The complex chloride (2-methylpyridinium)2[TbCl4(H2O)3]Cl has been prepared for the first time. (2-Methylpyridinium)2[TbCl4(H2O)3]Cl crystallizes monoclinically in the space group P21/n (Z=4) with a=1327.0 pm, b=886.3 pm, c=1911.3 pm and β=105.52°. The coordination polyhedron containing terbium is a pentagonal bipyramid [TbCl4(H2O)3]−. The magnetic behaviour of (2-methylpyridinium)2[TbCl4(H2O)3]Cl and (2-methylpyridinium)3[TbCl6] has been studied. The magnetic data are interpreted by ligand field calculations applying the angular overlap model.

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