Réaction du diméthyl(diazométhyl)phosphonate sur des glucides réducteurs: synthèse de glyco-1-ynitols
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Add time:08/20/2019 Source:sciencedirect.com
RésuméReaction of aldose derivatives with dimethyl(diazomethyl)phosphonate, generated in situ by methanolysis of dimethyl(1-diazo-2-oxopropyl)phosphonate, leads to glyco-1-ynitols derivatives. This synthesis presents two main advantages: it is a one-step synthesis, and tolerates free hydroxyl groups.
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