Thermal studies on piperidinium hexathiocyanatochromate(III)
-
Add time:08/24/2019 Source:sciencedirect.com
Piperidinium hexathiocyanatochromate(III), (pipH)3[Cr(NCS)6], was synthesized using the molten salt pipHSCN and was found to contain nitrogen-bonded thiocyanate. The (pipH)3[Cr(NCS)6] decomposes in the range 250–370°C with the primary reaction being complete disruption of the compound to Cr(NCS)3(s) and pipHSCN(g). The reaction appears to be zero order with an activation energy of 82.4 ± 6.0 kJ mol−1. Decomposition of Cr(NCS)3 takes place at higher temperatures, but the reaction is somewhat variable.
We also recommend Trading Suppliers and Manufacturers of potassium hexathiocyanatochromate(III) (cas 15530-47-9). Pls Click Website Link as below: cas 15530-47-9 suppliers
Prev:Synthesis and cytotoxic activity of gold(I) complexes containing phosphines and 3-benzyl-1,3-thiazolidine-2-thione or 5-phenyl-1,3,4-oxadiazole-2-thione as ligands
Next:Regular articleTitrimetric determination of microgram amounts of silver by thiocyanate amplification after precipitation as silver hexathiocyanatochromate(III)) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Chromium(III) heterocomplexes—II: Isothiocyanato-complexes of chromium(III) with benzimidazole and 2-methylbenzimidazole☆08/29/2019
- Thermal decomposition of analytically important thiocyanatochromates(III). Part 108/28/2019
- Solvent effects on the electronic spectrum of the hexathiocyanatochromate (III) anions. A revised octahedral crystal field splitting parameter for the thiocyanate ion08/27/2019
- Short communicationTitrimetric determination of microgram amounts of lead by thiocyanate amplification after precipitation as lead hexathiocyanatochromate(III)08/26/2019
- Regular articleTitrimetric determination of microgram amounts of silver by thiocyanate amplification after precipitation as silver hexathiocyanatochromate(III)08/25/2019
-
Health and Chemical more >
-
Related Products
- Potassium (2S,3S)-3-(ethoxycarbonyl)oxirane-2-carboxylate
- Potassium (4-formylphenyl)trifluoroborate
- Potassium (bromomethyl)trifluoroborate
- Potassium (R)-((3-ethoxy-1-methyl-3-oxoprop-1-enyl)amino)(4-hydroxyphenyl)acetate
- Potassium (R)-(4-hydroxyphenyl)((3-methoxy-1-methyl-3-oxoprop-1-enyl)amino)acetate
- Potassium (R)-[(3-ethoxy-1-methyl-3-oxoprop-1-enyl)amino]phenylacetate
- Potassium [(cyanomethyl)thio]acetate
- Potassium 1,2,3,6-tetrahydro-5-nitro-2,6-dioxopyrimidine-4-carboxylate
- Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate
- Potassium 2,3,3-trimethyl-3H-indole-5-sulfonate