Koch carbonylation using silver trifluoromethanesulfonate
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Add time:08/30/2019 Source:sciencedirect.com
Koch carbonylation was carried out using silver trifluoromethanesulfonate (AgOTf). Tertiary alcohols were transformed into the corresponding carboxylic acids in good yield under carbon monoxide atmosphere (5 MPa: initial pressure) at 150°C. It can be assumed that under these reaction conditions, a strong acid, in which a silver(I) cation participates, would be generated from AgOTf.
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