Modification of silicalite-1 by vinyltrimethoxysilane (cas 2768-02-7) (VTMS) and preparation of silicalite-1 filled polydimethylsiloxane (PDMS) hybrid pervaporation membranes
-
Add time:07/16/2019 Source:sciencedirect.com
In preparation of inorganic particles filled polymer membranes, coupling agents can help to improve the compatibility between inorganic filler and polymer matrix. In this paper, surface modification of silicalite-1 was performed by a coupling agent, vinyltrimethoxysilane (cas 2768-02-7) (VTMS), and hybrid pervaporation membranes were prepared by incorporating the unmodified or VTMS-modified silicalite-1 into polydimethylsiloxane (PDMS). The VTMS-modified silicalite-1 particles and hybrid membranes were characterized by FT-IR, 29Si CP MAS NMR, DSC, TGA, XRD and SEM. The results showed that the coupling agent VTMS was readily grafted on the surface of silicalite-1 by hydrolysis reaction and condensation reaction, and the chemical linking between the –CHCH2 group on the surface-modified silicalite-1 and –Si–H on the PDMS substantially eliminated the nonselective voids inside the membrane. When used to separate acetone, butanol, ethanol (ABE) from aqueous solution, a higher selectivity was obtained with the VTMS-modified silicalite-1/PDMS hybrid membrane. Moreover, the surface modification of silicalite-1 improved its dispersion in PDMS and increased the maximal loading of silicalite-1 in membrane preparation, and thus further enhanced the separation factor of the membrane.
▶ Silicalite-1 could be modified by vinyltrimethoxysilane (VTMS). The modification did not change the crystal framework of silicalite-1, but enhanced its hydrophobicity and affinity with polydimethylsiloxane (PDMS) matrix. ▶ VTMS modification helped to make interfacial void-free hybrid membranes with higher silicalite-1 loading. ▶ VTMS modification enhanced the selectivity of the silicalite-1/PDMS hybrid membrane in separating butanol from acetone, butanol and ethanol (ABE) aqueous solution by pervaporation.
We also recommend Trading Suppliers and Manufacturers of vinyltrimethoxysilane (cas 2768-02-7). Pls Click Website Link as below: cas 2768-02-7 suppliers
Prev:Surface modification of ammonium polyphosphate with vinyltrimethoxysilane (cas 2768-02-7): Preparation, characterization, and its flame retardancy in polypropylene
Next:Evaluation of the influence of experimental parameters in the formation of a vinyltrimethoxysilane (cas 2768-02-7) film on 1010 carbon steel through electrochemical impedance spectroscopy and contact angle techniques) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- An assessment of the corrosion protection of AA2024-T3 treated with vinyltrimethoxysilane (cas 2768-02-7)/(3-glycidyloxypropyl)trimethoxysilane07/21/2019
- Photofunctional binary and ternary Eu3+/Tb3+ hybrid materials with copolymer linkage methacrylic acid–vinyltrimethoxysilane (cas 2768-02-7) and 1,10-phenanthroline07/19/2019
- Creation of coating surfaces possessing superhydrophobic and superoleophobic characteristics with fluoroalkyl end-capped vinyltrimethoxysilane (cas 2768-02-7) oligomeric nanocomposites having biphenylene segments07/18/2019
- Evaluation of the influence of experimental parameters in the formation of a vinyltrimethoxysilane (cas 2768-02-7) film on 1010 carbon steel through electrochemical impedance spectroscopy and contact angle techniques07/17/2019
- Surface modification of ammonium polyphosphate with vinyltrimethoxysilane (cas 2768-02-7): Preparation, characterization, and its flame retardancy in polypropylene07/15/2019
- Holographic polymer dispersed liquid crystals using vinyltrimethoxysilane (cas 2768-02-7)07/14/2019
- vinyltrimethoxysilane (cas 2768-02-7)-modified zinc oxide quantum dots with tuned optical properties07/13/2019
- Synthesis and Characterization of vinyltrimethoxysilane (cas 2768-02-7)-Grafted Non-Swelling Clay07/12/2019
- Selective modification of kaolinite with vinyltrimethoxysilane (cas 2768-02-7) for stabilization of Pickering emulsions07/11/2019