Infrared photoreaction of 2-chloroethyltrifluorosilane
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Add time:09/07/2019 Source:sciencedirect.com
Infrared laser dissociation of 2-chloroethyltrifluorosilane has been studied in light of silicon isotopes separation. The reaction occurs via beta-elimination mechanism to yield ethylene and chlorotrifluorosilane as products. The dissociation has a relatively low energy barrier what was confirmed by high-level quantum chemical calculations. High enrichment of 30Si isotope was demonstrated.
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