Selective detection of pyrophosphate anion by a simple Cd(II) based terpyridine complex
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Add time:09/01/2019 Source:sciencedirect.com
A simple ratiometric terpyridine-Cd(ll) complex was synthesized by the treatment of CdCl2 with terpyridine ligand 4′-(4-N,N′-dimethylaminophenyl)-2,2′:6′,2″-terpyridine. The synthesized complex was found to act as a selective fluorescent chemosensor for pyrophosphate P2O74 − (PPi) over other anions like F−, Cl−, Br−, CO32 −, SO32 −, AcO−, NO2−, and H2PO4−. Furthermore, the receptor probe was also successfully employed in HeLa cell for PPi detection, which indicates this can be used as a chemosensor for cells.
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