Short CommunicationMagnetic nanoparticle supported triphenylphosphine ligand for the Rh-catalyzed hydroformylation reaction
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Add time:09/02/2019 Source:sciencedirect.com
A magnetic recyclable nano-triphenylphosphine (nano-TPP) ligand was synthesized by simply loading a dopamine-triphenylphosphine derivative onto the surface of super paramagnetic iron oxide nanoparticle (SPION). Via the cooperation between surface neighbor TPP units, nano-TPPs can bond to Rh atoms forming magnetic recyclable nano-TPPRh complexes to catalyze the hydroformylation reaction and can be reused for 20 times with the compensation of Rh salt.
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