CommunicationLigand-free nickel-catalyzed Kumada couplings of aryl bromides with tert-butyl Grignard reagents
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Add time:09/01/2019 Source:sciencedirect.com
A ligand-free nickel-catalyzed Kumada cross-coupling of aryl bromides and tert-butyl Grignard reagents led to the formation of a series of tert-butyl aryls in moderate to good yields, excellent tBu/iBu ratios, and good functional group compatibility. A radical coupling process is indicated and a mechanism with a Ni(I)-Ni(III) catalytic cycle is proposed.
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