Isobaric vapor-liquid equilibria for the extractive distillation of tert-butyl alcohol + water mixtures using 1-ethyl-3-methylimidazolium dicyanamide ionic liquid

Add time:09/02/2019    Source:sciencedirect.com

Isobaric vapor-liquid equilibria for the binary systems tert-butyl alcohol + water, and tert-butyl alcohol + 1-ethyl-3-methylimidazolium dicyanamide ([emim][DCA]), as well as the vapor-liquid equilibria for the tert-butyl alcohol + water + [emim][DCA] ternary system, have been obtained at 100 kPa using a recirculating still. The electrolyte nonrandom two-liquid (e-NRTL) model was successfully used for fitting the experimental data. The effect of [emim][DCA] on the tert-butyl alcohol + water system has been compared with that produced by other ionic liquids reported in the literature. From the results, [emim][DCA] appears as a good entrainer for the extractive distillation of this solvent mixture, causing the azeotrope to disappear at 100 kPa when the ionic liquid mole fraction is >0.095.

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