Short CommunicationCO bond formation via oxidative-coupling pathway in eutectic mixture of choline chloride/urea as a green solvent

Add time:09/08/2019    Source:sciencedirect.com

CO bond formation between terminal alkenes/benzyl alcohols as an arylcarboxy surrogate and carbonyl compounds in a biodegradable deep eutectic solvent (DES) based on choline chloride and urea was performed. By employment of TBAI as catalyst and TBHP as oxidant, various derivatives of carbonyl compounds were benzylated in α position in good to high yield at 90 °C. Moreover, α-oxybenzoylation of diethyl malonate with carboxylic acids was performed in the above-mentioned DES by employment of NaI as the catalyst and TBHP as the oxidant at 60 °C.

We also recommend Trading Suppliers and Manufacturers of 4-Chlorobenzoyl chloride (cas 122-01-0). Pls Click Website Link as below: cas 122-01-0 suppliers

Prev:Electrostatic influence of active-site waters on the nucleophilic aromatic substitution catalyzed by 4-chlorobenzoyl-CoA dehalogenase
Next:2-Hydroxy-4-Isopropylbenzaldehyde (cas 122-03-2), a potent partial tyrosinase inhibitor)