A contribution to the elucidation of the biosynthesis of 3-chloro-4-(3′-chloro-2′-nitrophenyl)-1H-pyrrole (pyrrolnitrin)
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Add time:09/08/2019 Source:sciencedirect.com
Selective openings of the ring B of the derivative hexapyrroloindol in basic conditions confirm the rearrangement of the tryptophan to aminoarylpyrrol, analogously to the step catalyzed by the enzyme prnB in the biosynthesis of pyrrolnitrin.
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