Enthalpy of formation of platinum hexafluoride (cas 13693-05-5)
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Add time:09/08/2019 Source:sciencedirect.com
Knudsen-cell mass spectrometry was used for the investigation of the gas-phase equilibrium: PtF4 + F2 = PtF6, generated within an effusion cell by heating a (Pt + TbF4) mixture. By use of the third law the following quantities at T = 298.15 K have been determined: ΔrHmo = −(152 ± 12) kJ·mol−1; ΔfHmo(PtF6, g) = −(676 ± 28) kJ·mol−1; ΔfHmo(PtF6, s, I) = −(714 ± 28) kJ·mol−1; ΔfHmo(PtF6, s, II) = −(722 ± 28) kJ·mol−1.
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