Microwave spectrum of Dichloroborane (cas 13701-67-2) (BHCl2)
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Add time:09/08/2019 Source:sciencedirect.com
The microwave spectrum of Dichloroborane (cas 13701-67-2) has been observed and the rotational constants of four isotopic species are determined as follows: A = 46911.09(7), B = 3185.937(10) and C = 2980.425(14) MHz for the normal species, A = 46747.14(8), B = 3099.543(14) and C = 2904.037(14)MHz for BHCl37Cl, A = 49302.05(24), B = 3185.536(32) and C = 2989.368(51) MHz for 10BHCl2 and A = 35153.18(9), B = 3186.026(15) and C = 2918.233(11) MHz for BDCl2. The following complete rs structure was determined: rs(BH) = 1.184(2) Å, rs(BCl) = 1.735(2) Å and ∠ ClBCl = 120.4(2)°. The hyperfine structure due to the two chlorine and one boron nuclei has been analysed.
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