Chiral Lewis acids derived from 1,8-naphthalenediylbis-(Dichloroborane (cas 13701-67-2)): Mechanistic aspects
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Add time:09/25/2019 Source:sciencedirect.com
Chiral Lewis acids derived from 1,8-Naphthalenediylbis(dichloroborane), a novel bidentate Lewis acid, have been found to be active catalysts for the asymmetric Diels-Alder reaction. Utilizing chiral ligands derived from amino acids, a range of enantioselectivities have been achieved with cyclopentadiene and various α,β-unsaturated aldehydes. Some mechanistic aspects of this novel asymmetric bidentate catalyst have been addressed.
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