Selective syntheses of novel highly functionalized β-aminocyclohexanecarboxylic acids
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Add time:09/25/2019 Source:sciencedirect.com
Highly functionalized β-aminocyclohexanecarboxylate regio- and stereoisomers were synthetized from racemic unsaturated bicyclic β-lactams via enzymatic resolution, selective transformation of the C–C double bond by stereoselective epoxidation, and regioselective oxirane ring opening with azide or cyanide as nucleophile.
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