A diversity oriented synthesis of D-ERYTHRO-SPHINGOSINE (cas 123-78-4) and siblings
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Add time:09/08/2019 Source:sciencedirect.com
An efficient building block-based synthetic protocol has been developed for the synthesis of 3-ketosphingoids with various chain lengths using cross metathesis of a Garner’s aldehyde-derived α,β-unsaturated ketone as the key step. Stereoselective reduction of the biomimetic precursors thus obtained provided D-ERYTHRO-SPHINGOSINE (cas 123-78-4) and truncated anaogues in good overall yields.
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