15-[(Z)-Phenylmethylidene]-7,14-dioxadispiro[5.1.5.2]pentadecanes: stereoselective one-pot assembly from cyclohexanones and phenylacetylene in a KOH/DMSO suspension
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Add time:09/08/2019 Source:sciencedirect.com
Cyclohexanones react with phenylacetylene in a KOH/DMSO suspension (80 °C, 1 h) to give unexpectedly phenylmethylidene dispirocyclic ketals, 15-[(Z)-phenylmethylidene]-7,14-dioxadispiro[5.1.5.2]pentadecanes, in 16–22% yields (along with the anticipated β,γ- and α,β-ethylenic ketones).
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