An easy access to diversely fused dioxa-2-aza-tricyclo[n.3.1.02,n]tetra/pentadecanes under solvent-free condition

Add time:09/09/2019    Source:sciencedirect.com

Efficient syntheses of phenyl/N-heterocycle fused 6,13-dioxa-2-aza-tricyclo[8.3.1.02,8]tetradecanes have been accomplished from 8-hydroxy quinoline derivatives under solvent-free condition, using basic alumina as the solid support. The methodology was successfully extended for the synthesis of corresponding pentadecane derivatives under similar reaction conditions. In terms of its general applicability, product yield, reaction time and effortless separation techniques, the methodology is more valuable compared to the solution phase protocols.

We also recommend Trading Suppliers and Manufacturers of Pentadecane, 7-methylene- (cas 13043-55-5). Pls Click Website Link as below: cas 13043-55-5 suppliers

Prev:15-[(Z)-Phenylmethylidene]-7,14-dioxadispiro[5.1.5.2]pentadecanes: stereoselective one-pot assembly from cyclohexanones and phenylacetylene in a KOH/DMSO suspension
Next:New cyclic aminals derived from rac-trans-1,2-diaminocyclohexane: synthesis and crystal structure of racemic 1,8,10,12-tetraazatetracyclo[8.3.1.1.8,1202,7] pentadecane and a route to its enantiomerically pure (R,R) and (S,S) isomers)