Synthesis of the tricyclo[9.3.1.03,8]pentadecane (ABC) ring system of taxane diterpenes
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Add time:09/26/2019 Source:sciencedirect.com
The synthesis of diketone 14 possessing the tricyclo[9.3.1.03,8]pentadecane (ABC) taxane ring system is described. This concise approach employs a Wacker oxidation, intramolecular aldol condensation-dehydration, and a highly exo-stereoselective intermolecular Diels-Alder reaction as key steps.
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