Synthesis of phenylacetic acids under rhodium-catalyzed carbonylation conditions
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Add time:09/09/2019 Source:sciencedirect.com
Benzyl halides are efficiently carbonylated to phenylacetic acids in the presence of a catalytic amount of the dimer of chloro(1,5-cyclooctadiene)rhodium(I) in formic acid. Under these reaction conditions, sensitive functionalities such as esters and nitriles are tolerated and the phenylacetic acids are obtained in good to high yields.
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