An organocatalytic synthesis of N-sulfonyl imines using Chloramine-T (cas 127-65-1) in aqueous medium
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Add time:09/25/2019 Source:sciencedirect.com
N-Sulfonyl imines have been synthesized in good to excellent yields from aldehydes and Chloramine-T (cas 127-65-1) using proline as an organocatalyst in aqueous medium at ambient temperature. The protocol is applicable to a wide range of aldehydes, especially enals exhibit remarkable efficiency in the reaction. The reaction presumably occurs via iminium activation and opens new avenues for the synthesis of N-sulfonyl imines under environmentally benign and mild conditions.
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