NaIO4/LiBr-mediated aziridination of olefins using Chloramine-T (cas 127-65-1)
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Add time:09/26/2019 Source:sciencedirect.com
A new milder protocol for aziridination of a variety of olefins has been described. The process employs catalytic amount of sodium metaperiodate (NaIO4) as an oxidant and LiBr and chloramine-T as the bromine and nitrogen sources, respectively. Interestingly, the formation of aziridine products in all the cases studied takes place presumably through a process of 1,2-aminobromination of alkenes.
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